Catalytic combustion of methane on aluminate-supported copper oxide

Citation
P. Artizzu et al., Catalytic combustion of methane on aluminate-supported copper oxide, CATAL TODAY, 47(1-4), 1999, pp. 83-93
Citations number
21
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
CATALYSIS TODAY
ISSN journal
09205861 → ACNP
Volume
47
Issue
1-4
Year of publication
1999
Pages
83 - 93
Database
ISI
SICI code
0920-5861(19990101)47:1-4<83:CCOMOA>2.0.ZU;2-Z
Abstract
Copper oxide has been deposited onto high surface area magnesium aluminate spinel prepared from alumina and magnesium nitrate. The catalytic propertie s of such a solid have been investigated in methane combustion. At the labo ratory scale a very good activity is observed (light-off of 530 degrees C) and no CO is detected. Aging at 1000 degrees C under water vapour has no in fluence on activity. The previous catalyst has been washcoated on monolith and tested on a rig either with methane or synthetic natural gas at very hi gh GHSV under conditions close to those of a gas turbine. In that case also , a good activity was observed. (C) 1999 Elsevier Science B.V. All rights r eserved.