A numerical analysis of NOx formation and control in radiatively/conductively-stabilized pulverized coal combustors

In an attempt to study ways for reducing NOx emissions from radiatively/con ductively-stabilized combustors (RCSC) for pulverized coal, a comprehensive conjugate heat and mass transfer and reaction kinetics model of that combu stor was developed. As compared with a much simpler three-reaction model, t he radiation intensity distribution obtained by the new model shows a subst antial decrease in the flame region. The analysis has shown that (1) the ef fect of a 10% deviation in the diffusion coefficients on the results was fo und to be negligible, indicating that the use of binary coefficients instea d of those for a multi-component system may be good enough in such combusti on modeling, (2) flame location was found to have little effect (similar to 6%), and internal wall emittance an insignificant effect, on NO emissions, (3) the mass fraction of these emissions could be lowered by lowering the flame temperature, accomplished by increasing the excess air ratio, (4) at the same time, the overall mass of NO emitted with the thicker lower-temper ature flames produced by such increases in excess air was much higher, indi cating that the RCSC with its capability for producing a high temperature t hin flame is much more effective for the reduction of NO emissions than low er temperature combustion alternatives. (C) 1998 Elsevier Science S.A. All rights reserved.