Ladder-type phthalocyanine conductor, [PXX][Co(Pc)(CN)(2)] (PXX = peri-xanthenoxanthene, Co(Pc)(CN)(2) = dicyano(phthalocyaninato)cobalt(III))

Authors
Takano, S Naito, T Inabe, T
Citation
S. Takano et al., Ladder-type phthalocyanine conductor, [PXX][Co(Pc)(CN)(2)] (PXX = peri-xanthenoxanthene, Co(Pc)(CN)(2) = dicyano(phthalocyaninato)cobalt(III)), CHEM LETT, (12), 1998, pp. 1249-1250
Citations number
9
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
12
Year of publication
1998
Pages
1249 - 1250
Database
ISI
SICI code
0366-7022(199812):12<1249:LPC[(=>2.0.ZU;2-F
Abstract
Electrochemical oxidation of PXX and [Co(Pc)(CN)(2)](-) in acetonitrile giv es a highly conducting crystal containing two-leg ladder chains of the part ially oxidized Co(Pc)(CN)(2) units. The doubling of the one-dimensional cha ins makes the electrical properties quite different from those in the singl e chain conductor.