2,4,6-tri-tert-butyl-1,3,5-triphosphate as an eta(6)-ligand in transition metal complexes

Authors
Binger, P Stutzmann, S Stannek, J Gabor, B Mynott, R
Citation
P. Binger et al., 2,4,6-tri-tert-butyl-1,3,5-triphosphate as an eta(6)-ligand in transition metal complexes, EUR J INORG, (1), 1999, pp. 83-86
Citations number
34
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
14341948 → ACNP
Issue
1
Year of publication
1999
Pages
83 - 86
Database
ISI
SICI code
1434-1948(199901):1<83:2AAEIT>2.0.ZU;2-F
Abstract
The eta(6)-1,3,5-triphosphabenzene transition metal complexes 12a,b, 14, an d 16 have been synthesized for the first time by the displacement of eta(6) -arena ligands (toluene, benzene and naphthalene) with 2,4,6-tri-tert-butyl -1,3,5-triphosphabenzene (9). The new complexes have been fully characteriz ed by a combination of elemental analysis, mass spectrometry, and H-1-, C-1 3- and P-31-NMR spectroscopy.