Design rules are proposed for achieving robust and reliable soldering in a
fluxless environment. The associated processes are discussed in relation to
the principal solders that are used in electronics manufacture. Essential
to the realization of a successful fluxless soldering process is a mutually
compatible selection of solder and finishes supplied on the components and
circuit board. This combination must ensure that the joint surfaces are ad
equately wetted by the solder whilst at the same time that the finishes do
not form intermetallic phases with the solder that are deleterious to the m
echanical integrity of the joint. On account of its good solderability and
resistance to oxidation, gold is frequently the preferred choice as a finis
h, particularly where the use of chemical fluxes is excluded. However, when
gold is used with a tin-rich solder, care must be taken to limit its thick
ness on the joint surfaces to prevent the catastrophic formation of brittle
AuSn4. Guidelines for the optimum thickness of the gold finish appropriate
to frequently used tin-rich solders are provided. Indium-based solders are
more tolerant to gold metallizations and they are a safer option where thi
cker electroplated gold coatings are used. Whilst indium forms up to three
intermetallic compounds with gold, they do not compromise joint integrity.