Jp. Feve et al., Second-harmonic generation properties of 2-amino-5-nitropyridinium-dihydrogenarsenate and -dihydrogenphosphate organic-inorganic crystals, IEEE J Q EL, 35(1), 1999, pp. 66-71
We present a comparative study of the linear and nonlinear optical properti
es of two isomorphous organic-inorganic crystals: the 2-amino-5-nitropyridi
nium-dihydrogenphosphate (2A5NPDP) and -dihydrogenarsenate (2A5NPDAs). We d
etermine accurate equations for the dispersion in wavelength of their princ
ipal refractive indices from direct prism measurements and from angular non
critically phase-matched second-harmonic generation (SHG) experiments. We d
educe the quadratic nonlinear coefficients d(15) and d(24) of each compound
from the phase-matched conversion efficiency of SHG experiments and find t
hat they are close to those of KTiOPO4.