ANODIC-OXIDATION OF THE SPIRO[4,9'-FLUORENYL]-2,6-DIPHENYLTHIOPYRAN -TOWARDS POLYPHENYLENE SUBSTITUTED BY THIOPYRYLIUM OR THIOPYRANYL FUNCTIONS

Authors
RAULTBERTHELOT J ROZE C
Citation
J. Raultberthelot et C. Roze, ANODIC-OXIDATION OF THE SPIRO[4,9'-FLUORENYL]-2,6-DIPHENYLTHIOPYRAN -TOWARDS POLYPHENYLENE SUBSTITUTED BY THIOPYRYLIUM OR THIOPYRANYL FUNCTIONS, Synthetic metals, 83(2), 1996, pp. 153-157
Citations number
12
Categorie Soggetti
Physics, Condensed Matter","Material Science","Polymer Sciences
Journal title
Synthetic metals → ACNP
ISSN journal
03796779
Volume
83
Issue
2
Year of publication
1996
Pages
153 - 157
Database
ISI
SICI code
0379-6779(1996)83:2<153:AOTS->2.0.ZU;2-C
Abstract
Anodic oxidation of the spiro [4,9'-fluorenyl]-2,6-diphenylthiopyran a t potential more anodic than 1.85 V (ref: Ag/0.1 M (Ag+, NO3-) in CH3C N) leads to the coating of the anode by an insoluble electroactive mat erial, which is described as a polyphenylene matrix substituted by thi opyrylium or thiopyran functions depending on the oxidation state.