The grain boundary structure of undoped InP polycrystals grown from the vap
our phase was characterized using electron diffraction and high-resolution
electron microscopy. Most grain boundaries were tilt boundaries even though
twist boundaries were also observed. The high-angle grain boundaries were
mainly {111} twin boundaries. Deviation of misorientation from the exact (1
11) twin relationship was accommodated by introduction of dislocations. Inc
oherent twin boundaries were also observed.