Gv. Benemanskaya et al., Electronic structure and local interactions on a Si(100)2x1 surface with submonolayer Ba overlayers, J EXP TH PH, 87(6), 1998, pp. 1167-1171
The electronic structure and ionization energy for the system Ba/Si(100)2 X
1 have been studied as functions of the submonolayer coverage. It is found
that there is an energy gap in the surface states spectrum and that the Ba
/Si(100)2 X 1 interface is semiconducting up to 1.5 monolayers of Ba. Two s
urface bands induced by Ba adsorption have been detected. The evolution of
the spectrum with increasing degree of Ba coverage points to the existence
of two nonequivalent "adsorption sites,'' which differ in binding energy by
0.11 eV. The development of the Ba-induced bands is found to terminate at
a coverage corresponding to the minimum ionization energy and close to one
monolayer. The adsorption bond is shown to have a primarily covalent charac
ter. (C) 1998 American Institute of Physics. [S1063-7761(98)01812-5].