F. Catara et al., Self-consistent determination of the one-body density matrix and particle-hole excitations, PHYS REV B, 58(24), 1998, pp. 16070-16075
We develop a procedure recently proposed for the treatment of correlations
in finite Fermi systems in a more consistent way than the random phase appr
oximation (RPA). The one-body density matrix in the correlated ground state
is now no more assumed to be diagonal in the Hartree-Fock basis. An expres
sion is rather provided where this quantity is expressed in terms of the X
and Y amplitudes of the particle-hole phonon operators. A set of RPA-like e
quations depending only on the one-body density matrix is then constructed
by means of the method of linearized equations of motion and solved via an
iterative procedure. The procedure is employed to calculate spectra and str
ength distributions of several neutral and charged Na and Li metal clusters
within the jellium approximation. Improvements are observed with respect t
o standard RPA calculations. [S0163-1829(98)06947-1].