The first metal-dmit polymer with 3D supramolecular networks. Synthesis and crystal structure of [(Et4N)(2){Ag4(dmit)(3)}center dot DMF](infinity) (dmit = 1,3-dithiole-2-thione-4,5-dithiolate)

Authors
Sheng, TL Wu, XT Wang, QM Gao, XC Lin, P
Citation
Tl. Sheng et al., The first metal-dmit polymer with 3D supramolecular networks. Synthesis and crystal structure of [(Et4N)(2){Ag4(dmit)(3)}center dot DMF](infinity) (dmit = 1,3-dithiole-2-thione-4,5-dithiolate), POLYHEDRON, 17(25-26), 1998, pp. 4519-4524
Citations number
16
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
POLYHEDRON
ISSN journal
02775387 → ACNP
Volume
17
Issue
25-26
Year of publication
1998
Pages
4519 - 4524
Database
ISI
SICI code
0277-5387(1998)17:25-26<4519:TFMPW3>2.0.ZU;2-M
Abstract
The first metal-dmit polymeric complex, [(Et4N)(2){Ag-4(dmit)(3)}. DMF](inf inity) has been synthesized and structurally characterized. The crystal of the complex is monoclinic with space group C2/c, a = 32.078(4), b = 11.791( 2), c = 29.409(4) Angstrom. beta = 124.14(1)degrees, V = 9206.8, Z = 8, R = 0.053, R-w = 0.061. In the complex, the S ... S contacts exist both intra- and inter-molecularly, through the intermolecular S ... S contacts shorter than 3.7 Angstrom the two-dimensional polymeric anions form a three-dimens ional unique supramolecular networks. (C) 1998 Elsevier Science Ltd. All ri ghts reserved.