M. Atreya et al., Effect of plasma treatment on the electrical and electroluminescent properties of poly(p-phenylene vinylene) light emitting diodes, POLYM DEGR, 63(1), 1999, pp. 53-59
The influence of argon and oxygen plasma treatments of the polymer surfaces
on the electrical and electroluminescent properties of poly(p-phenylene vi
nylene) (PPV) light emitting diodes (LEDs) has been studied. It was observe
d that mild Ar plasma treatment of the polymer prior to deposition of the c
athode could reduce the electroluminescent intensity of the PPV LED by an o
rder of magnitude. Similar results were observed for the oxygen plasma trea
ted samples. Attempts were made to correlate this plasma-induced degradatio
n phenomenon of the electroluminescent properties of PPV with changes in th
e surface chemical structures of the polymer, as revealed by the angle-reso
lved X-ray photoelectron spectroscopy (XPS). (C) 1998 Elsevier Science Ltd.
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