H. Keypour et al., Isolation of ternary complex precursors and partially condensed intermediates to macrocyclic complexes of nickel(II) and copper(II), TRANSIT MET, 23(5), 1998, pp. 609-613
Reaction in unheated solutions between metal salts, bis(3-aminopropyl)amine
(dpt) and 2,6-diacetylpyridine (dap) gives the ternary complexes [M(dpt)(d
ap)](2+) - (M = Ni or Cu), in which no Schiff-base condensation has occurre
d. Cyclisation requires long standing or heating. For tris(3-aminopropyl)am
ine and nickel(II), X-ray crystallography shows that reaction in MeOH can b
e stopped after condensation of one carbonyl and one amine group to give a
coordinated open-chain hexadentate ligand, an intermediate in the formation
of the fully condensed macrocycle. With the 2-(aminoethyl)-4-(butylamino)a
mine (ebt), the butylamine groups are involved in intermolecular condensati
on with carbonyl groups from adjacent units, giving oligomeric or polymeric
complexes.