Synthesis, magnetic and spectral studies of iron(III), cobalt(II,III), nickel(II), copper(II) and zinc(II) complexes of 2-formylpyridine N(4)-antipyrinylthiosemicarbazone
Ak. El-sawaf et al., Synthesis, magnetic and spectral studies of iron(III), cobalt(II,III), nickel(II), copper(II) and zinc(II) complexes of 2-formylpyridine N(4)-antipyrinylthiosemicarbazone, TRANSIT MET, 23(5), 1998, pp. 649-655
2-Formylpyridine N(4)-antipyrinylthiosemicarbazone and its metal complexes
have been synthesized and characterized. Elemental analyses, molar conducti
vities, magnetic measurements and spectral (i.e., i.r., electronic, n.m.r.
and e.s.r.) studies have been used to characterize the complexes. The i.r.
spectra show that the thiosemicarbazones behave as bidentate or tridentate
ligands either in the thione or thiolato form. Ligand field parameters have
been calculated and the proposed stereochemistries are based on the variou
s physical and spectral methods.