The present study has been carried out in a completely filled gravity pipe,
61 km long, which transports reclaimed urban wastewater (RUWW), for crop i
rrigation in the island of Tenerife (Spain), at an average water velocity o
f 0.4 m/s. Due to the long residence time of the reclaimed wastewater in th
e pipe (40 hours), anaerobic conditions usually appear. and chemical transf
ormation of reclaimed wastewater occurs during transportation, especially s
ulfide generation. Field studies have been conducted from November 1994 to
January 1997. The variation in sulfide and oxidation-reduction potential (O
RP) among other parameters during wastewater transportation have been repor
ted. The object of this work is to study the kinetics of the sulfide genera
tion in a full scale reclaimed wastewater pipe, in order to obtain a foreca
sting equation of sulfide generation, and to compare this equation with tho
se previously proposed for raw wastewater sewers. Equations obtained from t
his research differ quite from those previously proposed for sewers. This c
an be due to the reclaimed wastewater used in this system, which has a very
much lower organic matter content than raw wastewater. (C) 1998 Published
by Elsevier Science Ltd. All rights reserved.