Determination of iodide and iodate by ion chromatography with postcolumn reaction and UV/visible detection

Citation
Y. Bichsel et U. Von Gunten, Determination of iodide and iodate by ion chromatography with postcolumn reaction and UV/visible detection, ANALYT CHEM, 71(1), 1999, pp. 34-38
Citations number
14
Categorie Soggetti
Chemistry & Analysis","Spectroscopy /Instrumentation/Analytical Sciences
Journal title
ANALYTICAL CHEMISTRY
ISSN journal
00032700 → ACNP
Volume
71
Issue
1
Year of publication
1999
Pages
34 - 38
Database
ISI
SICI code
0003-2700(19990101)71:1<34:DOIAIB>2.0.ZU;2-#
Abstract
Iodide and iodate can be determined by two new methods using anion-exchange chromatography with postcolumn reaction and UV/visible detection. Iodide i s determined as IBr2- at 249 mn. Iodate is determined as I-3(-) at 288 nm. The analyses can be run completely automatically and do not require any sam ple pretreatment, The detection limits for iodide and iodate are 0.1 mu g/L . The methods have been successfully applied to determine iodide and iodate in several mineral waters and in drinking water as well as for the determi nation of iodide in table salt.