Electronic excitation spectra of the alkali-metal (AM) (Na,Cs)-adsorbed Si(
111)7 x 7 surfaces have been investigated by using high-resolution electron
energy loss spectroscopy. We find that AM induces metal-semiconductor tran
sitions at the early stage of adsorption by completely filling half-filled
Si adatom dangling-bend states. A loss peak of energy less than 0.31 eV app
ears as a precursor of the semi conducting phases, which disappears with in
creasing coverage, resulting in the formation of energy gaps of 0.43 eV and
1.08 eV for Cs and Na, respectively. Both Cs- and Na-adsorbed surfaces bec
ome metallic at saturation, in sharp contrast with the semiconducting K-sat
urated surface. We discuss the physical origin of the AM-induced loss peaks
and its implications for the electrical phase transitions.