The influence of thermal diffusion on the structure of hydrogen-air and met
hane-ah names is investigated numerically using complex chemistry and detai
led transport models. All the transport coefficients in the mixture, includ
ing thermal diffusion coefficients, are evaluated using new algorithms whic
h provide, at moderate computational costs, accurate approximations derived
rigorously from the kinetic theory of gases. Our numerical results show th
at thermal diffusion is important for an accurate prediction of name struct
ure.