Synthesis of diphenylphosphine palladium complexes

Authors
Giannandrea, R Mastrorilli, P Nobile, CF
Citation
R. Giannandrea et al., Synthesis of diphenylphosphine palladium complexes, INORG CHIM, 284(1), 1999, pp. 116-118
Citations number
4
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANICA CHIMICA ACTA
ISSN journal
00201693 → ACNP
Volume
284
Issue
1
Year of publication
1999
Pages
116 - 118
Database
ISI
SICI code
0020-1693(19990115)284:1<116:SODPC>2.0.ZU;2-9
Abstract
The synthesis of Pd(PPh2H)(2)Cl-2 is achieved by reaction of Pd(PhCN)(2)Cl- 2 with PPh2H in toluene at room temperature. Pd(PPh2H)(2)Cl-2 spontaneously transforms into [PdCl(mu-PPh2)(PPh2H)](2) when let in solution and affords Pd(PPh2H)(4) when treated with two equivalents of PPh2H in ethanol. (C) 19 99 Elsevier Science S.A. All rights reserved.