Electrolytic partial fluorination of organic compounds. 30. Drastic improvement of anodic monofluorination of 2-substituted 1,3-oxathiolan-5-ones using the novel fluorine source Et4NF center dot 4HF

Authors
Higashiya, S Narizuka, S Konno, A Maeda, T Momota, K Fuchigami, T
Citation
S. Higashiya et al., Electrolytic partial fluorination of organic compounds. 30. Drastic improvement of anodic monofluorination of 2-substituted 1,3-oxathiolan-5-ones using the novel fluorine source Et4NF center dot 4HF, J ORG CHEM, 64(1), 1999, pp. 133-137
Citations number
38
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANIC CHEMISTRY
ISSN journal
00223263 → ACNP
Volume
64
Issue
1
Year of publication
1999
Pages
133 - 137
Database
ISI
SICI code
0022-3263(19990108)64:1<133:EPFOOC>2.0.ZU;2-W
Abstract
The highly regioselective anodic monofluorination of 2-substituted 1,3-oxat hiolan-5-ones was successfully carried out using a novel supporting electro lyte, Et4NF . 4HF, while use of a conventional supporting electrolyte, Et3N . 3HF, resulted in no formation or extremely low yields of the fluorinated products.