Solid state coordination chemistry of the copper cyanide organoamine system: hydrothermal synthesis and structural characterization of [{Cu-2(bpy)(2)(CN)}(2)Cu-5(CN)(7)]center dot 0.17H(2)O

Authors
Chesnut, DJ Kusnetzow, A Zubieta, J
Citation
Dj. Chesnut et al., Solid state coordination chemistry of the copper cyanide organoamine system: hydrothermal synthesis and structural characterization of [{Cu-2(bpy)(2)(CN)}(2)Cu-5(CN)(7)]center dot 0.17H(2)O, J CHEM S DA, (24), 1998, pp. 4081-4083
Citations number
16
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
ISSN journal
03009246 → ACNP
Issue
24
Year of publication
1998
Pages
4081 - 4083
Database
ISI
SICI code
0300-9246(199812):24<4081:SSCCOT>2.0.ZU;2-O
Abstract
The hydrothermal reaction of CuCN, KCN, 2,2'-bipyridyl (bpy) and water yiel ds [{Cu-2(bpy)(2)(CN)}(2)Cu-5(CN)(7)]. 0.17H(2)O 1, a two-dimensional coppe r-cyano network intercalated by [(bpy)(2)(Cu)(2)(CN)](+) cations and water of crystallization.