Chalcogen abstraction from dithiadiazolyl and diselenadiazolyl platinum complexes: crystal structure of a novel metallaheterocycle

Authors
Feeder, N Less, RJ Rawson, JM Smith, JNB
Citation
N. Feeder et al., Chalcogen abstraction from dithiadiazolyl and diselenadiazolyl platinum complexes: crystal structure of a novel metallaheterocycle, J CHEM S DA, (24), 1998, pp. 4091-4093
Citations number
18
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
ISSN journal
03009246 → ACNP
Issue
24
Year of publication
1998
Pages
4091 - 4093
Database
ISI
SICI code
0300-9246(199812):24<4091:CAFDAD>2.0.ZU;2-#
Abstract
The open-shell complexes, (PhCNEEN)Pt(dppe) (E = S or Se) decompose via a c halcogen abstraction process coupled with N-protonation to yield the novel 10 pi metalla-heterocyclic cations {[PhCN(H)N(H)E]Pt(dppe)}(+): the seleniu m complex is characterised by X-ray crystallography as its chloride salt.