Preparation and thermal decomposition of copper(II) complexes with 4-methylimidazole

Citation
A. Turek et M. Olczak-kobza, Preparation and thermal decomposition of copper(II) complexes with 4-methylimidazole, J THERM ANA, 54(1), 1998, pp. 133-137
Citations number
14
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
ISSN journal
13886150 → ACNP
Volume
54
Issue
1
Year of publication
1998
Pages
133 - 137
Database
ISI
SICI code
1388-6150(1998)54:1<133:PATDOC>2.0.ZU;2-5
Abstract
Simple and mixed compounds of the formulae Cu(4-Meim)(2), CuSal(4-Meim), Cu Sal(4-Meim)(2) and CuSalox(4-Meim)(2), where 4-Meim=4-methylimidazole, Sal= (OC6H4COO)(2-), Salox=(OC6H4CHNO)(2-) have been prepared. Thermal decomposi tion reactions have been established on the basis of thermal and X-ray anal yses of these compounds. The pyrolysis proceeds in several (3-4) stages con nected with the mass loss and exothermic effects. As a result of the last s tage of decomposition CuO is formed.