Thermodynamic properties of aqueous solution of 1,N-2-(prop-1-ene-1,2-diyl)acyclovir

Citation
A. Zielenkiewicz et al., Thermodynamic properties of aqueous solution of 1,N-2-(prop-1-ene-1,2-diyl)acyclovir, J THERM ANA, 54(1), 1998, pp. 237-241
Citations number
7
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
ISSN journal
13886150 → ACNP
Volume
54
Issue
1
Year of publication
1998
Pages
237 - 241
Database
ISI
SICI code
1388-6150(1998)54:1<237:TPOASO>2.0.ZU;2-#
Abstract
A description of experimental thermodynamic data of aqueous solutions of 1, N-2-(prop-1-ene-1,2-diyl)acyclovir in the range of molality 0.008237-0.0183 3 1 mol kg(-1) is provided on the basis of differential scanning adiabatic calorimetry and densimetry. The enthalpy of hydration from the experimental enthalpy of solution and the enthalpy of sublimation was determined (Delta (m)H(hydr)= -124.1 kJ mol(-1)). The non-linear variations of apparent molar heat capacities with temperature and concentration were observed. The appa rent molar volumes increase with temperature in the range of 25-45 degrees C.