Vv. Ovchinnikov et al., Thermochemistry of heteroatomic compounds - X. The thermochemistry of solution and solvation of substituted alkylphosphonic derivatives, J THERM ANA, 54(1), 1998, pp. 305-309
The enthalpies of vaporization of different classes of phosphorylated alcoh
ols and amines were determined from their enthalpies of solution in hexane
and carbon tetrachloride. The enthalpies of specific (hydrogen-bond) intera
ction with the solvents (chloroform and pyridine) of derivatives containing
X-H groups (X=O or N) in the alpha-position to the P=O group were detemine
d. The results were explained in terms of the spatial structure of such com
pounds.