PERBORATE OXIDATION OF IODIDE-ION

Authors
KARUNAKARAN C MUTHUKUMARAN B KAMALAM R
Citation
C. Karunakaran et al., PERBORATE OXIDATION OF IODIDE-ION, Polish Journal of Chemistry, 71(4), 1997, pp. 474-479
Citations number
4
Categorie Soggetti
Chemistry
Journal title
Polish Journal of Chemistry → ACNP
ISSN journal
01375083
Volume
71
Issue
4
Year of publication
1997
Pages
474 - 479
Database
ISI
SICI code
0137-5083(1997)71:4<474:POOI>2.0.ZU;2-4
Abstract
In aqueous acidic solution perborate generates hydrogen peroxide and t he oxidation of iodide ion to iodine at 35 degrees C follows the rate law -d[oxidant]/dt = (0.367 [I-][H+] + 1.96x10(-2)[I-] + 9.78x10(-4)) [oxidant]. The mechanism of oxidation is discussed.