Renormalization of Helfrich's interactions between fluid membranes in a lyotropic lamellar phase by addition of amphiphilic

Citation
F. Castro-roman et al., Renormalization of Helfrich's interactions between fluid membranes in a lyotropic lamellar phase by addition of amphiphilic, PHYS REV L, 82(1), 1999, pp. 109-112
Citations number
23
Categorie Soggetti
Physics
Journal title
PHYSICAL REVIEW LETTERS
ISSN journal
00319007 → ACNP
Volume
82
Issue
1
Year of publication
1999
Pages
109 - 112
Database
ISI
SICI code
0031-9007(19990104)82:1<109:ROHIBF>2.0.ZU;2-G
Abstract
We study the effect of an amphiphilic block copolymer on the thermodynamic properties of a lyotropic lamellar phase into which it is incorporated. A q uantitative analysis of the small angle neutron scattering spectra of these samples shows that the polymer strongly enhances the stabilizing Helfrich' s interactions between membranes, by increasing the effective bilayer thick ness. The smectic compressibility of the lamellar phase becomes insensitive to the addition of salt, as soon as the Debye length is smaller than the t hickness of the layer of copolymer adsorbed onto the membrane. This effect is similar to the "steric repulsion" of anchored polymer layers in colloida l dispersions. [S0031-9007(98)08129-0].