Lattice constants of solid solution microstructures: The case of nanocrystalline Pd-H

We present an analysis of the effect of interface stress on strain in bulk in an open system with a large interface-to-volume ratio, at equilibrium wi th the solute at a controlled chemical potential. The results are relations for interface stress and for solute concentration in the bulk as a functio n of measurable parameters: interfacial "stretch" and changes in the lattic e constant. Stretch models a change in the average normal component of the interatomic spacing at interfaces. X-ray diffraction and dilatometry provid e experimental data showing a significant variation of grain boundary stres s and stretch in nanocrystalline Pd-H with hydrogen chemical potential. [S0 031-9007(98)08132-0].