Gd. Pizarro et al., Application of a synthetic water-soluble poly(N-maleyl glycine-co-acrylamide) as polychelatogen for inorganic ions in aqueous solutions, POLYM BULL, 41(6), 1998, pp. 687-694
The water-soluble poly(N-maleyl glycine-co-acrylamide) (P(MG-co-Am)) reagen
t with strong complexing properties for the inorganic ions Cr(III), Co(II),
Zn(II), Ni(II), Cu(II), Cd(II), Pb(II), Hg(II), As(V), and Se(IV) was inve
stigated in aqueous phase in conjunction with membrane filtration using the
Liquid-phase Polymer-based Retention (LPR) technique. The P(MG-co-Am) was
shown to be useful for retention of different inorganic ions and their sepa
ration from elements not bound to the polymeric reagent. The inorganic ion
interaction with the hydrophilic polymer was determined as a function of pH
and filtration factor. At higher pH, the copolymer can be applied to the s
eparation and preconcentration of most of the inorganic ions. Viscosimetric
measurements of the copolymers were performed in the presence of metal ion
s at different pH values.