Ma. Baig et al., HIGH-RESOLUTION MEASUREMENT AND MULTICHANNEL QUANTUM-DEFECT THEORY ANALYSIS OF THE ODD-PARITY J=1 SERIES IN MERCURY, Journal of the Optical Society of America. B, Optical physics, 14(4), 1997, pp. 731-736
We report new high-resolution photoabsorption measurements of the prin
cipal and the intercombination series in neutral mercury by use of a 3
-m vacuum spectrograph equipped with a 6000-line/mm holographic gratin
g and synchrotron radiation as the background source of the continuum.
The perturbations observed in these Rydberg series are parameterized
by a three-channel quantum-defect theory. An improved value of the fir
st ionization potential is derived as 84 184.15 +/- 0.07 cm(-1). (C) 1
997 Optical Society of America.