T. Hata et al., Heteroepitaxial growth of YSZ films on Si(100) substrate by using new metallic mode of reactive sputtering, VACUUM, 51(4), 1998, pp. 583-590
Yttria-stabilized zirconia (YSZ) thin film is deposited by reactive magnetr
on sputtering from a composite Zr-Y target in an Ar-O-2 gas mixture. Variou
s hysteresis curves, such as the deposition rate and Zr+, Y+, ZrO+, YO+ ion
s, are observed as a function of the oxygen flow rate (O-2/Ar). In the meta
llic mode, metallic films are deposited and in the oxide mode YSZ films are
deposited In order to control the reaction in reactive sputtering we prote
cted the metallic target from, oxidation by using a target cover with a 20
mm-diameter aperture. It was successful in depositing YSZ films in the meta
llic mode which has ten times higher deposition rate than the oxide mode. I
n this mode it was successful to growth the YSZ film heteroepitaxially on p
-(100)Si. The substrate temperature was 800 degrees C, and full width at ha
lf maximum (FWHM) of the rocking curve was 1.08 degrees The initial stage o
f epitaxial formation was observed by using the X-ray diffraction pattern,
the reflected high energy electron diffraction (RHEED) pattern, and the cro
ss-sectional transmission electron microscope (XTEM) photograph. (C) 1998 P
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