Since DC magnetron sputtering was introduced for the manufacturing of optic
al thin film systems on large area glass substrates, coating processes have
suffered from poor long term stability and low deposition rates. After lon
g years of intensive development work, today AC (midfrequency) powered twin
magnetron arrangements are capable to overcome these drawbacks.
During the past two years much data has been collected on AC reactive depos
ition of SiO2, Si3N4, Ta2O5, TiO2, SnO2, and ZnO. SiO2 and TiO, the most pr
ominent candidates for optical interference coatings, can be deposited on l
arge scale at rates exceeding 5 nm/s in a stable continuous process for mor
e than 300 hours. The deposition rates for SnO2 and ZnO are in the range of
10 nm/s. High density, low surface roughness and very good optical propert
ies of all deposited materials result from bombardment of the growing film
by a high flux of energetic ions.
The paper gives a survey on recent results with special emphasis on TiO2 an
d SnO2 layers. New applications like antire-flective-antistatic coatings ar
e presented. Enhanced performance and high resistance against environmental
attacks indicate that AC sputtering will play a major part in the future o
f PVD technology. (C) 1998 Elsevier Science Ltd. All rights reserved.