Thermodynamics of polyacethylene in the temperature range 0-340 K

Authors
Bykova, TA Lebedev, BV Belov, GP Belov, DG
Citation
Ta. Bykova et al., Thermodynamics of polyacethylene in the temperature range 0-340 K, VYSO SOED, 40(12), 1998, pp. 2040-2047
Citations number
38
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A & SERIYA B
ISSN journal
05075475 → ACNP
Volume
40
Issue
12
Year of publication
1998
Pages
2040 - 2047
Database
ISI
SICI code
0507-5475(199812)40:12<2040:TOPITT>2.0.ZU;2-P
Abstract
For cis- and trans-poly(acetylene)s, the temperature dependences of the hea t capacities were measured by adiabatic vacuum calorimetry in the 5-335 K r ange, and the thermodynamic functions C(p)degrees, H degrees(T)-H degrees(0 ), S degrees(T)-S degrees(0), Phi TB G degrees(T)-H degrees(0) were calcula ted in the 0-330 K range. New results combined with the published data were used to determine the thermodynamic parameters for the reactions of poly(a cetylene) preparation from acetylene, benzene, cyclooctatetraene, PVC, and PVA.