The thermal conductivity of a high conductivity metallic LaB6 single crysta
l was measured in the temperature range between 0.7 K and 30 K. The strikin
g point of the observed temperature dependence is the non - linear behaviou
r of thermal conductivity at lowest temperatures, where a linear dependence
is expected. Further measurements of electrical conductivity and of therma
l conductivity in magnetic field suggest that the non - linearity originate
s from a scattering mechanism which leads to a decrease of the electronic c
omponent of the thermal conductivity. Scattering processes of conduction el
ectrons by phonons and by magnetic impurities are discussed.