The physicochemical characterisation and determination of atmospheric parti
cle composition requires two major steps: sampling and chemical analysis. T
he adequacy between the characteristics of the sample and the analytical te
chnique is essential. In this paper; different analytical processes to char
acterise the global composition and especially the inorganic part of the at
mospheric particulate matter are discussed The potentiality of surface anal
ysis such as XPS applied to particle characterisation is also presented.