Physical and chemical characterization of atmospheric aerosols by atomic force microscopy

A new approach to the measurement of the size distribution of atmospheric p articles as a function of chemical reactivity is demonstrated. In this meth od, particles are collected on an atomically fiat mica substrate and imaged using atomic force microscopy. The particle size distribution is obtained from analysis of the image. The sample is then repeatedly exposed to a reac tive gas such as ozone or oxygen atoms and reimaged. The dimensions of orga nic and graphitic (soot) particles are found to shrink at different rates d ue to formation of volatile products, while inorganic particles remain unch anged. Using this approach, it is possible to classify particles as organic , graphitic, or inorganic and to obtain the size distribution for each chem ical class.