Using an original modulation technique, the electron spin-lattice relaxatio
n have been investigated in two noncommon metals: YBa2Cu3Ox, high-T-c mater
ial doped with 1% Gd, and Rb1C60, linear polymer phase fulleride. In the fi
rst case, the Korringa-like temperature dependence of the Gd3+ longitudinal
relaxation time T-1 is found for x = 6.59 in a wide temperature range 4.2
< T < 200 K, both above and below T-c = 56 K. At x = 6.95 (T-c = 90 K), the
T-1 behavior within 50 < T < 200 K is evidently affected by spin gap openi
ng with the gap value of about 240 K. At 200 K, an unexpected acceleration
of the relaxation rate takes place, suggesting some change in the relaxatio
n mechanism. The data are discussed in terms of the Barnes-Plefke theory wi
th allowance made for microscopic separation of the normal and superconduct
ing phases. In Rb1C60, the evolution of the ESR line and relaxation rates h
ave been studied accurately in the range of the metal-insulator transition
(below 50 K). Interpretation is suggested which takes into account breaking
down the relaxation bottleneck due to opening of the energy gap near the F
ermi surface. The gap value of about 100 cm(-1) is estimated from the analy
sis of relaxation rates, lineshape and spin susceptibilities.