Structure elucidation, packing, and solid-state behavior of the Eglinton-Galbraith dimer

Citation
Uhf. Bunz et V. Enkelmann, Structure elucidation, packing, and solid-state behavior of the Eglinton-Galbraith dimer, CHEM-EUR J, 5(1), 1999, pp. 263-266
Citations number
41
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY-A EUROPEAN JOURNAL
ISSN journal
09476539 → ACNP
Volume
5
Issue
1
Year of publication
1999
Pages
263 - 266
Database
ISI
SICI code
0947-6539(199901)5:1<263:SEPASB>2.0.ZU;2-K
Abstract
Crystal structure, packing behavior, and solid-state activity of the cyclic dimer 1 of ortho-diethynylbenzene are described. When crystallized in the presence of TCNQ or hexafluorobenzene, 1 forms novel 1:1 molecular complexe s in the solid state. The flat guests are inserted between the disklike mol ecules of 1 so that mixed stacks are formed.