Fluorine-related defects in 30-keV BF2+-implanted Si were probed using
monoenergetic position beams. From measurements of Doppler broadening
profiles of the annihilation radiation as a function of incident posi
tron energy and those of lifetime spectra of positrons, depth profiles
of defects and the species of the defects were determined. For an as-
implanted specimen, the major species of the defects below the amorpho
us region was identified to be divacancies. Upon rapid thermal anneali
ng above 700 degrees C, solid phase epitaxial growth of the amorphous
region started, but no shift of the depth profile of defects detected
by the positron annihilation technique was observed. During the regrow
th of the amorphous region, vacancy-fluorine complexes were introduced
. The complexes between vacancy clusters and fluorine atoms were obser
ved even after 1100 degrees C annealing.