A correlation between the chemical structure of azoic coupling components (
hereafter referred to as azotols) and their affinity for cotton has been at
tempted. The theoretically computed correlation equations of the practical
affinity with the van der Waals surface, the molecular volume and the hydro
phobicity are reported. The hypothesis of microcrystalline multilayered mic
elles' implication in the sorption of azotols to a cellulose support is sus
tained. (C) 1998 Elsevier Science Ltd. All rights reserved.