Structure of endo-2,3-homotroponeFe(CO)(3) and synthesis of optically active endo-1,2-homoheptafulvaleneFe(CO)(3) and endo-1,2-homoheptafulveneFe(CO)(3) derivatives

Authors
Morita, N Kurita, M Ito, S Asao, T Kabuto, C Ueno, M Sato, T Sotokawa, H Watanabe, M Tajiri, A
Citation
N. Morita et al., Structure of endo-2,3-homotroponeFe(CO)(3) and synthesis of optically active endo-1,2-homoheptafulvaleneFe(CO)(3) and endo-1,2-homoheptafulveneFe(CO)(3) derivatives, ENANTIOMER, 3(6), 1998, pp. 453-461
Citations number
13
Categorie Soggetti
Chemistry
Journal title
ENANTIOMER
ISSN journal
10242430 → ACNP
Volume
3
Issue
6
Year of publication
1998
Pages
453 - 461
Database
ISI
SICI code
1024-2430(1998)3:6<453:SOEASO>2.0.ZU;2-B
Abstract
The structure of endo-2,3-homotroponeFe(CO)(3) was established by X-ray ana lysis. Using the inclusion complex method, enantioresolution of 2,3-homotro pone was carried out. Starting from this optically active 2,3-homotropone, optically active endo-1,2-homoheptafulvaleneFe(CO)(3) and endo-1,2-homohept afulvene Fe(CO)(3) derivatives were prepared for the first time.