Ms. Lin et al., COEXISTENCE OF ANTIFERROMAGNETIC ORDER AND SUPERCONDUCTIVITY WITH T-NHIGHER THAN T-C IN DYNI2B2C, Physica. C, Superconductivity, 249(3-4), 1995, pp. 403-408
A superconducting transition temperature T-c of 3.8 K with an onset as
high as 5.2-5.5 K was reported for quaternary borocarbide DyNi2B2C wi
th a high antiferromagnetic Neel temperature T-N around 10.1-10.8 K. N
o reentrant behavior was observed down to 0.3 K demonstrating a perfec
t coexistence between superconductivity and antiferromagnetic order. A
superconducting upper critical field H-c2(0) of 3.0 kG, lower critica
l field H-c1(0) of 200 G and a Ginzburg-Landau parameter K of 3.7 were
derived. A broad T-c transition points to a possible small T-c varyin
g homogeneity range of DyNi2-alphaB2-betaC1-delta in the phase diagram
. The magnetic entropy S-m of 10.3 J/mol K or 90% Rln 4 indicates anti
ferromagnetic ordering of Dy3+ with a quadruplet ground state in the t
etragonal crystal field. Two field-induced weak-ferromagnetic-like tra
nsitions with a field of around 1 T were observed at 2 K.