SYNTHESIS AND CHARACTERIZATION OF C70BR14

Authors
WAIDMANN G JANSEN M
Citation
G. Waidmann et M. Jansen, SYNTHESIS AND CHARACTERIZATION OF C70BR14, Zeitschrift fur anorganische und allgemeine Chemie, 623(4), 1997, pp. 623-626
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
623
Issue
4
Year of publication
1997
Pages
623 - 626
Database
ISI
SICI code
0044-2313(1997)623:4<623:SACOC>2.0.ZU;2-6
Abstract
C70Br14 was obtained by bromination of fullerene C-70 in liquid bromin e or the solvents 1,1,2,2-tetrachlorethane and CS2, respectively. The compound was characterized by elemental analysis, thermal analysis, C- 13-solid-state-NMR and powder diffraction. The lattice parameters are a=32.09(2), b=10.731(7), c=18.135(6) Angstrom, beta=110.92(4)degrees, V=5834(4) Angstrom(3), Z=4. At room temperature C70Br14 decomposes slo wly to less bromine containing samples. Thermal analysis (heating rate 5 degrees/min) shows decomposition to C-70 and Br-2 at 134,9 degrees C.