THE REACTION OF P3N3CL4(NH2)(2) WITH HCL - THE CRYSTAL-STRUCTURE OF P3N3CL5(NH2)

Authors
ALBERTI M BRINEK J MAREK J TOUZIN J
Citation
M. Alberti et al., THE REACTION OF P3N3CL4(NH2)(2) WITH HCL - THE CRYSTAL-STRUCTURE OF P3N3CL5(NH2), Zeitschrift fur anorganische und allgemeine Chemie, 623(4), 1997, pp. 637-641
Citations number
34
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
623
Issue
4
Year of publication
1997
Pages
637 - 641
Database
ISI
SICI code
0044-2313(1997)623:4<637:TROPWH>2.0.ZU;2-L
Abstract
P3N3Cl5(NH2) in high purity and a good yield can be obtained by the re action of P3N3Cl4(NH2)(2) With gaseous HCl in acetonitrile. If diethyl ether or dichlormethane is used as a solvent, a salt-like compound [P3 N3Cl4H(NH2)(2)]Cl-+(-) is formed as a microcrystalline product instead of P3N3Cl5(NH2). The crystal structure of P3N3Cl5(NH2) was determined by X-ray structure analysis. Vibrational spectra and thermic behavior of both P3N3Cl5(NH2) and [P3N3Cl4H(NH2)(2)]Cl-+(-) are also briefly d iscussed.