By means of X-rap diffraction and thermal analysis on the systems 2-fIuoron
aphthalene - 2-naphthol and naphthalene - 2-naphthol, it is shown that the
form in which 2-naphthol crystallizes from the melt is identifiable with th
e typical form of naphthalene, Thus, there is second compound in the naphth
alenic series for which this form proves to be more stable than the structu
rally bordering one preferred by 2-fluoronaphthalene and most of the simple
beta-substituted derivatives.