Cyanoethylation of jute fibers in the form of nonwoven fabric was studied,
and these chemically modified fibers were used to wake jute-polyester compo
sites. The dynamic mechanical thermal properties of unsaturated polyester r
esin (cured) and composites of unmodified and chemically modified jute-poly
ester were studied by using a dynamic mechanical analyzer over a wide tempe
rature range. The data suggest that the storage modulus and thermal transit
ion temperature of the composites increased enormously due to cyanoethylati
on of fiber. An increase of the storage modulus of composites, prepared fro
m chemically modified fiber, indicates its higher stiffness as compared to
a composite prepared from unmodified fiber. It is also observed that incorp
oration of jute fiber (both unmodified and modified) with the unsaturated r
esin reduced the tan delta peak height remarkably. Composites prepared from
cyanoethylated jute show better creep resistance at comparatively lower te
mperatures. On the contrary, a reversed phenomenon is observed at higher te
mperatures (120 degrees C and above). Scanning electron micrographs of tens
ile fracture surfaces of unmodified and modified jute-polyester composites
clearly demonstrate better fiber-matrix bonding in the case of the latter.
(C) 1999 John Wiley & Sons, Inc.