The solar H Lyman-alpha line is, through O-2 photodissociation, an importan
t source of O(D-1) production throughout the mesosphere and lower thermosph
ere. To ascertain the energy balance in this altitude region, it is necessa
ry to know the O(D-1) yield across the solar H Lyman-alpha feature, since H
Lyman-alpha absorption by O-2 at similar to 80 km accounts for a substanti
al fraction of the solar radiation absorbed in the mesosphere. An earlier l
aboratory study had provided a value of 0.44+/-0.05 for the O(D-1) yield at
the center of the solar H Lyman-alpha line, where the profile shows a mini
mum in intensity due to strong self-reversal of the line. Using tunable las
er radiation, we have determined the O(D-1) yield from O-2 photodissociatio
n across the entire H Lyman-alpha profile from 121.2 to 121.9 nm, at a spec
tral resolution of 0.0015 nm (1 cm(-1)). The results reveal a strongly wave
length-dependent window in the O(D-1) yield, the origins of which are expla
ined using calculations based on a coupled-channel Schrodinger-equations mo
del of the O-2 photodissociation. The calculations, which show significant
isotopic dependence near H Lyman-alpha, predict that the depth of the quant
um-yield window will increase significantly as the temperature is lowered.
(C) 1999 American Institute of Physics. [S0021-9606(99)00604-2].