Most classification schemes and analyses of estuarine and exchange flows us
e only salinity as a tracer. Temperatures are generally ignored. However, a
proper understanding of the effects of surface heating can explain observe
d seaward changes in the slope of temperature-salinity correlations. A theo
ry is proposed relating changes in temperature and salinity with transport
and mixing parameters in a two-layer exchange flow. Results show that along
-channel changes in the slope of T-S correlations are virtually independent
of vertical mixing but are directly related to horizontal layer transport.
Changes in the layer salinities can be related to various ratios of horizo
ntal and vertical transports. Combining these two features of the theory pe
rmits a diagnostic determination of Lagrangian transport and mixing from st
andard hydrographic observations of layer temperature and salinity and an e
stimate of the surface heat input. The theory is applied to observations ma
de through the spring/neap tidal cycle of mixing in Hare Strait, British Co
lumbia.