T. Tsuboi et al., Structure of As-prepared and annealed porous silicon surfaces studied by nuclear magnetic resonance spectroscopy, J ELCHEM SO, 146(1), 1999, pp. 372-375
Structures of as-prepared and annealed porous silicon samples have been cha
racterized by Si-29 nuclear magnetic resonance (NMR) spectroscopy. Magnetic
shielding tensors have also been calculated using ab initio molecular orbi
tal calculations to help the characterization. After the annealing at 300 d
egrees C for 4 h, the NMR peak position shifted slightly and the chemical s
hia anisotropy increased. Hydrogen desorption during the annealing gives (S
iH)(2) dimer structure from SiH2 configuration. The assignments of NMR sign
als are as follows: -94 ppm due to SM, -85 ppm due to SiH2 and about -85 pp
m due to (SiH)(2). The (SiH)(2) dimer has large chemical shift anisotropy a
nd small magnetic shielding, which are caused by the strained conformation
of the dimer. (C) 1999 The Electrochemical Society. S0013-4651(98)04-077-4.
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