On heterometallic ferrocenyl compounds of gold and platinum

Authors
Jacob, K Zanello, P Voigt, F Fontani, M
Citation
K. Jacob et al., On heterometallic ferrocenyl compounds of gold and platinum, MONATS CHEM, 129(12), 1998, pp. 1213-1223
Citations number
17
Categorie Soggetti
Chemistry
Journal title
MONATSHEFTE FUR CHEMIE
ISSN journal
00269247 → ACNP
Volume
129
Issue
12
Year of publication
1998
Pages
1213 - 1223
Database
ISI
SICI code
0026-9247(199812)129:12<1213:OHFCOG>2.0.ZU;2-P
Abstract
The syntheses, properties, and chemical shifts of the heterometal gold(I) c omplexes FcNAu . P(C(6)H(4)C1-4)(3) (1), FcN'[Au . PPh3](2) (2), and Fc'[Au . PPh3](2) (3) are reported. The electrochemical behaviour of complexes 1 and 3 is compared with that of the related platinum derivatives (FcN)(2)Pt (4) and FcNPtCl . PPh3 (5). Cyclovoltammetric measurements confirm reversib le one-electron transfers.